Xing Lehong*,Meng Fanxu,Hao Yungui,et al.Effect of pH value on hydrogen evolution property of nickel coating of electroplating[J].Plating & Finishing,2023,(8):20-25.[doi:10.3969/j.issn.1001-3849.2023.08.004]
pH值对电镀镍镀层析氢性能的影响
- Title:
- Effect of pH value on hydrogen evolution property of nickel coating of electroplating
- Keywords:
- electrodeposition ; nickel coating ; hydrogen evolution reaction ; catalytic activity
- 分类号:
- TQ116.2
- 文献标志码:
- A
- 摘要:
- 在氨磺酸体系中，改变镀液 pH 值在紫铜表面制备镍镀层。通过扫描电镜（ SEM ）、线性极化曲线（ LSV ）、塔菲尔曲线（ Tafel ）、电化学阻抗谱（ EIS ）和计时电位法（ CP ）等方法对镍镀层的微观形貌、析氢性能和稳定性进行了测试。结果表明，当镀镍液的 pH 值为 3.8 时，镍镀层结晶细致且均匀，优化后的镍镀层暴露出更多的电催化析氢活性位点，在碱性电解液中表现出最佳的析氢性能，同时具有良好的析氢稳定性。
- Abstract:
- ： In the sulfamate plating system ， the nickel coating was prepared on the red copper surface with different pH values. The micromorphology ， hydrogen evolution property and stability for nickel coatings were characterized using scanning electron microscopy （ SEM ）， linear polarization curve （ LSV ）， Tafel curve ， electrochemical impedance spectroscopy （ EIS ） and chronopotentiometry （ CP ） . The results showed that when the pH value of nickel plating solution was 3.8 ， the crystallization of nickel coating was fine and uniform ， and the optimized nickel coating exposed more active sites for electrocatalytic hydrogen evolution ， it showed the best hydrogen evolution catalytic activity in alkaline electrolyte. Moreover ， the coating had good stability in hydrogen evolution reaction.
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备注/Memo
收稿日期： 2022-11-23 修回日期： 2023-01-27 作者简介： 邢乐红（ 1983 ―），女，博士，副教授，主要从事金属表面处理、化学电源等方面的研究， email ： xinglehonghit@126.com 基金项目： 黑龙江省自然科学基金联合引导项目（ LH2022B023 ， JJ2022LH0472 ）；牡丹江师范学院青年骨干项目（ QN2022007 ）；黑龙江省基本科研业务费科研项目（ 1452ZD008 ）；牡丹江师范学院研究生课程思政高质量建设项目（高等电化学课程思政项目）；牡丹江师范学院研究生科技创新项目（ kjcx2022-068mdjnu ）；牡丹江师范学院大学生创新创业训练计划项目（ 202210233001 ）