Wu Xianhong,Liu Cansen*,Li Jinyan,et al.Study on friction behavior of WS 2 /TiO 2 enhanced cobalt-based composite coatings[J].Plating & Finishing,2023,(8):38-45.[doi:10.3969/j.issn.1001-3849.2023.08.007]
WS 2 /TiO 2 增强钴基复合镀层的摩擦行为研究
- Title:
- Study on friction behavior of WS 2 /TiO 2 enhanced cobalt-based composite coatings
- 关键词:
- 电沉积; Co-WS 2 /TiO 2 复合镀层; 摩擦学
- Keywords:
- electrodeposition ; Co-WS 2 /TiO 2 composite coating ; tribology
- 分类号:
- TG178
- 文献标志码:
- A
- 摘要:
- 采用电沉积法制备钴 - 二硫化钨 / 二氧化钛（ Co-WS 2 /TiO 2 ）复合镀层。通过扫描电镜、激光共聚焦显微镜、 X 射线衍射仪、拉曼光谱和摩擦试验机等系统研究了 WS 2 、 TiO 2 单独和复合添加对镀层微观形貌、相结构、硬度和摩擦行为的影响及其机理。结果表明， WS 2 /TiO 2 的协同作用赋予 Co-WS 2 /TiO 2 复合镀层最高的硬度（约为 538 HV ）及最好的减摩、耐磨性能，平均摩擦系数约为 0.16 ，磨损率约为 1.01×10 -7 mm 3 / （ N·m ）。
- Abstract:
- ： Cobalt-tungsten disulfide/titanium dioxide （ Co-WS 2 /TiO 2 ） composite coatings were prepared by electrodeposition. The effects and mechanisms of individual and combined addition of WS 2 and TiO 2 on the microstructure ， phase structure ， hardness and tribological behavior of resultant coatings were systematically studied by scanning electron microscope ， laser confocal microscope ， X-ray diffractometer ， Raman spectroscopy and friction testing machine. The results show that synergistic effect of WS 2 /TiO 2 endows Co-WS 2 /TiO 2 composite coating with the highest hardness of about 538 HV and the best anti-friction and anti-wear properties with an average friction coefficient of about 0.16 and wear rate of about 1.01×10 -7 mm 3 / （ N·m ）， respectively.
参考文献/References:
[1] 雒建斌 . 超滑与摩擦起源的探索 [J]. 科学通报 , 2020, 65(27): 2967-2978, 2966.
[2] Okonkwo B O, Jeong C, Jang C. Advances on Cr and Ni electrodeposition for industrial applications-A review[J]. Coatings, 2022, 12(10): 1555.
[3] Fathi M, Safavi M S, Mahdavi S, et al. Co-P alloy matrix composite deposits reinforced by nano-MoS 2 solid lubricant: An alternative tribological coating to hard chromium coatings[J]. Tribology International, 2021, 159: 106956.
[4] Akram A, Tara N, Khan M A, et al. Enhanced remediation of Cr 6+ in bacterial-assisted floating wetlands[J]. Water and Environment Journal, 2020, 34: 970-978.
[5] Cardinal M F, Castro P A, Baxi J, et al. Characterization and frictional behavior of nanostructured Ni-W-MoS 2 composite coatings[J]. Surface and Coatings Technology, 2009, 204(1-2): 85-90.
[6] 安娜 , 花珂 , 史洪源 , 等 . TC4 钛合金表面电沉积 Co-W/MoS 2 复合镀层及摩擦磨损性能研究 [J]. 电镀与精饰 , 2022, 44(9): 63-70.
[7] Zhang H, Zhang N, Fang F. Fabrication of high-performance nickel/graphene oxide composite coatings using ultrasonic-assisted electrodeposition[J]. Ultrasonics Sonochemistry, 2020, 62: 104858.
[8] 高辉 , 刘伟杰 . 2A12 铝合金电沉积 Ni-Co-MoS 2 复合镀层的耐磨性能研究 [J]. 电镀与精饰 , 2020, 42(10): 1-5.
[9] Chen Z, Wagner J, Turq V, et al. Surfactant-assisted electrodeposition of Au-Co/WS 2 self-lubricating coating from WS 2 suspended cyanide electrolyte[J]. Journal of Alloys and Compounds, 2020, 829: 154585.
[10] He Y, Sun W T, Wang S C, et al. An electrodeposited Ni-P-WS 2 coating with combined super-hydrophobicity and self-lubricating properties[J]. Electrochimica Acta, 2017, 245: 872-882.
[11] Liu B, Yan S, He Y, et al. Research for electrodeposited superhydrophobic Ni-W-WS 2 coating and its anticorrosion and wear resistance[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 655: 130236.
[12] Sivadipoor I, Ashrafizadeh F. Synthesis and tribological behaviour of electroless Ni-P-WS 2 composite coatings[J]. Applied Surface Science, 2012, 263: 314-319.
[13] He Y, Wang S, Sun W, et al. Synthesis and properties of electrodeposited Ni-Co/WS 2 nanocomposite coatings[J]. Coatings, 2019, 9(2): 148.
[14] 赵龙志 , 王怀 , 赵明娟 , 等 . TiO 2 包覆 CNTs 复合纳米线的制备研究 [J]. 兵器材料科学与工程 , 2020, 43(2): 1-5.
[15] 王小红 , 刘豪 , 蒋焰罡 , 等 . 纳米 TiO 2 颗粒对 Ni-W-P 合金镀层性能的影响 [J]. 表面技术 , 2022, 51(1): 86-92, 104.
[16] 牛犇 , 易耀勇 , 易江龙 , 等 . TiO 2 添加对高锰钢堆焊层组织和性能的影响 [J]. 金属热处理 , 2016, 41(12): 52-57.
[17] 李长春 , 姜新华 , 肖祥定 , 等 . Ni-P-WC 和 Ni-P-SiC 复合镀层的耐磨和耐蚀性能比较 [J]. 材料保护 , 2021, 54(9): 59-62.
[18] 应丽霞 , 李正辉 , 刘冠男 , 等 . TiO 2 纳米粒子对 Ni-PTFE 镀层微观组织结构和性能的影响研究 [J]. 功能材料 , 2015, 46(6): 6031-6034.
[19] Yousefi E, Sharafi S, Irannejad A. The structural, magnetic, and tribological properties of nanocrystalline Fe-Ni permalloy and Fe-Ni-TiO 2 composite coatings produced by pulse electro co-deposition[J]. Journal of Alloys and Compounds, 2018, 753: 308-319.
[20] Wang L, Gao Y, Xu T, et al. A comparative study on the tribological behavior of nanocrystalline nickel and cobalt coatings correlated with grain size and phase structure[J]. Materials Chemistry and Physics, 2006, 99(1): 96-103.
[21] Liu C S, Wei D D, Xu R S, et al. Electroplated Co-Ni/WS 2 composite coating with excellent tribological and anticorrosion performance[J]. Tribology Transactions, 2020, 63(5): 857-866.
[22] Safavia M S, Tanhaei M, Ahmadipour M F, et al. Electrodeposited Ni-Co alloy-particle composite coatings: A comprehensive review[J]. Surface and Coatings Technology, 2020, 382: 125153.
[23] Luo T, Wei X W, Zhao H Y, et al. Tribology properties of Al 2 O 3 /TiO 2 nanocomposites as lubricant additives[J]. Ceramics International, 2014, 40(7): 10103-10109.
[24] Zhang Y L, Chen F, Zhang Y, et al. Influence of graphene oxide additive on the tribological and electrochemical corrosion properties of a PEO coating prepared on AZ31 magnesium alloy[J]. Tribology International, 2020, 146: 106135.
[25] Gustavsson F, Jacobson S. Diverse mechanisms of friction induced self-organisation into a low-friction material -An overview of WS 2 tribofilm formation[J]. Tribology International, 2016, 101: 340-347.
相似文献/References:
[1]张冰怡,张莎莎*,姚正军,等.电沉积Ni-W纳米晶镀层制备与显微硬度研究[J].电镀与精饰,2019,(8):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
ZHANG Bingyi,ZHANG Shasha*,YAO Zhengjun,et al.Preparation and Microhardness of Electrodeposited Ni-W Nanocrystalline Coatings[J].Plating & Finishing,2019,(8):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
[2]雷同鑫,鞠 辉,张长科,等.电镀Ni-W-P合金在钻杆接头上的应用[J].电镀与精饰,2019,(10):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
LEI Tongxin,JU Hui,ZHANG Changke,et al.Application of Ni-W-P Alloy Prepared by Electroplating to Tool Joints[J].Plating & Finishing,2019,(8):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
[3]李晓峰*,孟 芳,董会超,等.电沉积法制备掺铋金属锌及其性能表征[J].电镀与精饰,2020,(1):12.[doi:10.3969/j.issn.1001-3849.2020.01.003]
LI Xiaofeng*,MENG Fang,DONG Huichao,et al.Electrodeposited Preparation of Bi-Doped Metal Zinc and Its Performance Characterization[J].Plating & Finishing,2020,(8):12.[doi:10.3969/j.issn.1001-3849.2020.01.003]
[4]张永霞,王 玫,方 华*,等.Co3O4/碳纳米管复合膜的超级电容器性能[J].电镀与精饰,2020,(2):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
ZHANG Yongxia,WANG Mei,FANG Hua*,et al.Co3O4/Carbon Nanotube Composite Film for Supercapacitor and Its Performances[J].Plating & Finishing,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
[5]侯珂珂,陈新华,张万强,等.电沉积法制备仿生超疏水滤网及其油水分离性能[J].电镀与精饰,2020,(4):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
HOU Keke,CHEN Xinhua,ZHANG Wanqiang,et al.Preparation of Biomimetic Superhydrophobic Filter Screen by Electrodeposition and the Oil-Water Separation Performance[J].Plating & Finishing,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
[6]肖成龙,梁世雍,于兆勤*.可控阵列微柱超疏水表面实验研究[J].电镀与精饰,2020,(7):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
XIAO Chenglong,LIANG Shiyong,YU Zhaoqin*.Experimental Study on Superhydrophobic Surface of Controllable Array Microcolumns[J].Plating & Finishing,2020,(8):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
[7]徐 超,王淼宇,周建波,等.电沉积Ni-Mo-Fe-La合金析氢电极的工艺研究[J].电镀与精饰,2020,(8):7.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
XU Chao,WANG Miaoyu,ZHOU Jianbo,et al.Study on Electrodeposition Process of Ni-Mo-Fe-La Alloy Hydrogen Evolution Electrode[J].Plating & Finishing,2020,(8):7.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
[8]高 辉,刘伟杰*.2A12铝合金电沉积Ni-Co-MoS2复合镀层的耐磨性能研究[J].电镀与精饰,2020,(10):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
GAO Hui,LIU Weijie*.Research on Wear Resistance of Ni-Co-MoS2 Composite Coating Electrodeposited on 2A12 Aluminium Alloy[J].Plating & Finishing,2020,(8):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
[9]王 羽,刘励昀,杜荣斌*,等.添加剂MPS、DDAC、Cl-对铜箔电沉积的影响[J].电镀与精饰,2021,(5):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
WANG Yu,LIU Liyun,DU Rongbin*,et al.Effects of Additives MPS， DDAC and Cl- on the Copper Foil[J].Plating & Finishing,2021,(8):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
[10]杨惠良*.硫酸盐镀液中紫铜电沉积Ni-Co/WC复合镀层的工艺条件优化[J].电镀与精饰,2021,(6):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]
YANG Huiliang*.Optimization of Process Conditions for Electrodeposition of Ni-Co/WC Composite Coatings on Red Copper from Sulfate Bath[J].Plating & Finishing,2021,(8):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]
备注/Memo
收稿日期： 2023-01-10 修回日期： 2023-02-09 作者简介： 吴先红（ 1988 ―），女，硕士研究生， email ： 2544412964@qq.com * 通信作者： 刘灿森， email ： liucs@gdut.edu.cn 基金项目： 广州市科技计划（ 202201010495 ）；大学生创新创业训练项目（ xj2022118450648 ）?/html>