Zhang Jinyuan,Zhang Jingli,Bai Zhongbo,et al.Research status of titanium anode coating for electrolytic copper foil[J].Plating & Finishing,2023,(12):95-102.[doi:doi ： 10.3969/j.issn.1001-3849.2023.12.014]
电解铜箔用钛阳极涂层的研究现状
- Title:
- Research status of titanium anode coating for electrolytic copper foil
- Keywords:
- titanium anode ; electrolytic copper foil ; coating ; preparation method
- 分类号:
- TG178
- 文献标志码:
- A
- 摘要:
- 电解铜箔是电子行业的重要原材料。金属钛因其密度低、耐腐蚀性能好是制备电解铜箔用阳极的理想基材。本文对电解铜箔用钛阳极进行了概述、介绍了钛阳极贵金属涂层制备方法、钛阳极贵金属涂层改性方法及电解铜箔用钛阳极涂层现存问题，并提出了今后的发展方向。
- Abstract:
- ： Electrolytic copper foil is an important raw material for the electronics industry. Titanium metal is an ideal substrate for the preparation of anodes for electrolytic copper foil because of its low density and good corrosion resistance. This paper provides an overview of titanium anodes for electrolytic copper foil ， introduces the preparation method of titanium anode precious metal coating ， the modification method of titanium anode precious metal coating and the existing problems of titanium anode coating for electrolytic copper foil ， and puts forward the future development direction.
参考文献/References:
[1] 杨森 . 锂电池用高性能超薄电解铜箔的研究 [D]. 常州 : 常州大学 , 2022.
[2] Ma X L, Li Y Z, Yao E D, et al. Microstructure and properties of electrolytic copper foil with different thicknesses[J]. Rare Metal Materials and Engineering, 2019, 48(9): 2905-2909.
[3] 文雯 , 周国云 , 王翀 , 等 . 面向 5G 通信的电解铜箔表面粗化处理研究 [J]. 印制电路信息 , 2021, 29(S2): 358-364.
[4] Yu W Y, Lin C Y, Li Q Y, et al. A novel strategy to electrodeposit high-quality copper foils using composite additive and pulse superimposed on direct current[J]. Journal of Applied Electrochemistry, 2021, 51(3): 489-501.
[5] 孟凡英 . 锂离子电池现状及研究趋势 [J]. 科学技术创新 , 2019(5): 153-154.
[6] 徐龙 , 安聪 , 黄国平 . 基于新能源电池用高延伸率超薄铜箔工艺研发 [J]. 电子质量 , 2021(11): 114-118.
[7] Guzman D, Dubray G, Aguilar C, et al. Mechanochemical processing of IrO 2 -Ta 2 O 5 : An alternative route for synthesizing Ir and Ir(Ta)O 2 solid solution[J]. Boletin De La Sociedad Espanola De Ceramica Y Vidrio, 2021, 60(2): 109-118.
[8] Yan Z W, Zhao Y W, Zhang Z Z, et al. A study on the performance of IrO 2 -Ta 2 O 5 coated anodes with surface treated Ti substrates[J]. Electrochimica Acta, 2015, 157: 345-350.
[9] Zhang Y B, Ma Q Q, Fen K K, et al. Effects of microstructure and electrochemical properties of Ti/IrO 2 -SnO 2 -Ta 2 O 5 as anodes on binder-free asymmetric supercapacitors with Ti/RuO 2 -NiO as cathodes[J]. Ceramics International, 2020, 46(11): 17640-17650.
[10] 路雨禾 , 王伟 , 路殿坤 , 等 . 电解沉积用尺寸稳定型钛阳极的研究现状 [J]. 有色金属 ( 冶炼部分 ), 2020(11): 18-24.
[11] Mirseyed S F, Jafarzadeh K, Rostamian A, et al. A novel approach to the role of iridium and titanium oxide in deactivation mechanisms of a Ti/(36 RuO 2- X IrO 2 -(64 - X ) TiO 2 ) coating in sodium chloride solution[J]. Corrosion Science, 2022, 206: 110481.
[12] Wang M, Kim B, Han D S, et al. Electrocatalytic activity of nanoparticulate TiO 2 coated onto Ta-doped IrO 2 /Ti substrates: Effects of the TiO 2 overlayer thickness[J]. Chemical Engineering Journal, 2021, 425: 131435
[13] Kumar D, Gupta S K. Electrochemical oxidation of direct blue 86 dye using MMO coated Ti anode: modelling, kinetics and degradation pathway[J]. Chemical Engineering and Processing-Process Intensification, 2022, 181: 109127.
[14] Li X Y, Cheng S, Xu R, et al. Structure-activity relationships of TiO 2 nanoflower-coated porous Ti anodes in electro-catazone process[J]. Chemical Engineering Journal Advances, 2022, 11: 100347.
[15] Xu W T, Haarberg G M, Seland F, et al. The durability of the thermally decomposed IrO 2 -Ta 2 O 5 coated titanium anode in a sulfate solution[J]. Corrosion Science: The Journal on Environmental Degradation of Materials and its Control, 2019, 150(4): 76-90.
[16] 林琳 , 田林 , 庄晓东 , 等 . 试析涂层钛阳极的研制及在电解锌中的应用 [J]. 冶金管理 , 2020(21): 23-24.
[17] 徐海清 , 曾繁波 , 胡耀红 , 等 . PCB 水平电镀用涂层钛阳极的可修复性研究 [J]. 电镀与涂饰 , 2021, 40(1): 59-64.
[18] Mo F, Zhou Q X, Hou Z L, et al. Efficient electro-catalyzed PMS activation on a Fe-ZIF-8 based BTNAs/Ti anode: An in-depth investigation on anodic catalytic behavior[J]. Environment International, 2022, 169: 107548.
[19] B?micke W, Rammelsberg P, Spatola G, et al. The effect of titanium anodization on the bond strength of 10-methacryloyloxydecyl dihydrogen phosphate (10-MDP) resin cement[J].The International Journal of Prosthodontics, 2022, 10: 11607.
[20] Weeranoppanant P, Palanuwech M. Effects of ceramic thickness and titanium anodization on esthetic outcomes of lithium disilicate ceramic over titanium alloys[J]. The European Journal of Prosthodontics and Restorative Dentistry, 2022, 31(1): 40-49.
[21] Zhao J Y, Chi Z X, Dong H, et al. Degradation of desphenyl chloridazon in a novel synergetic electrocatalytic system with Ni-Sb-SnO 2 /Ti anode and PEDOT/PSS-CNTs modified air diffusion cathode[J]. Journal of Cleaner Production, 2021, 300: 126961.
[22] 于晓艳 , 李婧 , 杨晓霜 , 等 . 钛阳极涂层对污泥电渗透脱水的影响及脱水工艺参数的优化 [J]. 江西化工 , 2022, 38(3): 107-112.
[23] Wang Y Y, Pierce R, Shi H H, et al. Electrochemical degradation of perfluoroalkyl acids by titanium suboxide anodes [J]. Environmental Science: Water Research & Technology, 2020, 6(1): 144-152.
[24] Li D, Yi L, Gan Z, et al. Preparation of electrolyzed oxidizing water by TiO 2 doped IrO 2 -Ta 2 O 5 electrode with high selectivity and stability for chlorine evolution[J]. Journal of Electroanalytical Chemistry, 2019, 832: 459-466.
[25] 丁杰 . 高电流密度下电解铜箔添加剂的研究 [D]. 南昌 : 南昌大学 , 2022.
[26] 徐海清 , 胡耀红 , 陈力格 , 等 . 电解铜箔用涂层钛阳极表面结垢的去除 [J]. 电镀与涂饰 , 2015, 34(4): 201-205.
[27] 周腾腾 , 徐成飞 , 王俊 , 等 . 高级氧化技术在废水处理中的研究进展 [J]. 山东化工 , 2021, 50(6): 263-264, 267.
[28] Ma X Q, Zhou Y, Cao L Yet al. Enhancing the electrochemical activity of an IrO x -Ta 2 O 5 /Ti anode via radio frequency-driven rapid plasma annealing[J]. Surface & Coatings Technology, 2020, 396: 125961.
[29] Xu W T, Haarberg G M, Seland F, et al. The durability of the thermally decomposed IrO 2 -Ta 2 O 5 coated titanium anode in a sulfate solution[J]. Corrosion Science, 2019, 150: 76-90.
[30] 叶张军 . IrO 2 -Ta 2 O 5 /Ti 析氧阳极制备工艺改进及性能 [D]. 杭州 : 浙江工业大学 , 2009.
[31] Xu L K, Xin Y L, Wang J T. A comparative study on IrO 2 -Ta 2 O 5 coated titanium electrodes prepared with different methods[J]. Electrochimica Acta, 2009, 54(6): 1820-1825.
[32] Hosseini M G, Hosseini M M, Ahadzade I. The use of silica in IrO 2 -based DSA type electrode: An efficient approach to construct cost-effective, potent electrodes for oxygen evolution reaction[J]. Materials Chemistry and Physics, 2022, 285: 126086.
[33] 彭浩然 , 魏宗平 , 王欣 , 等 . 钌锡氧化物复合涂层的制备与相结构特点 [J]. 金属热处理 , 2010, 35(8): 18-21.
[34] 张惠灵 , 胡春华 , 徐亮 , 等 . 钛基二氧化铅电极的制备及其对甲基橙的降解 [J]. 环境科学与技术 , 2007(9): 28-30, 38, 116-117.
[35] Herrada R A, Acosta-Santoyo G, Sepulveda-Guzman S, et al. IrO 2 -Ta 2 O 5 vertical bar Ti electrodes prepared by electrodeposition from different Ir:Ta ratios for the degradation of polycyclic aromatic hydrocarbons[J]. Electrochimica Acta, 2018, 263: 353-361.
[36] 陶自春 , 潘建跃 , 罗启富 . 铂中间层的制备及对铱钽涂层钛阳极性能的影响 [J]. 材料科学与工程学报 , 2004, 22(2): 240-244.
[37] 潘建跃 , 孙凤梅 , 罗启富 . 钛阳极磁控溅射钽的工艺研究 [J]. 材料保护 , 2004, 37(10): 26-28.
[38] 杨国生 , 徐海清 . Sb 2 O 3 掺杂对钛基 IrO 2 -Ta 2 O 5 -Sb 2 O 3 涂层阳极性能的影响 [J]. 电镀与涂饰 , 2022, 41(10): 679-682.
[39] 李思平 , 邓昭平 . 锑掺杂二氧化钛的制备及其可见光催化性能 [J]. 电子元件与材料 , 2005(9): 33-35.
[40] 张铁军 , 李坚 , 何洪 , 等 . 锑掺杂对钒钛系催化剂低温脱硝活性的影响 [J]. 燃料化学学报 , 2017, 45(6): 740-746.
[41] 庄晓东 , 田林 , 林琳 , 等 . 含 Mn 涂层钛阳极的制备及性能 [J]. 有色金属工程 , 2022, 12(7): 33-38.
[42] 刘晓军 , 刘贵昌 . IrO 2 -MnO 2 中间层 Ti/RuO 2 -TiO 2 -SnO 2 电极制备及性能 [J]. 稀有金属材料与工程 , 2012, 41(1): 54-57.
[43] Yan Z W, Li G, Wang J S, et al. Electro-catalytic study of IrO 2 -Ta 2 O 5 coated anodes with pretreated titanium substrates[J]. Journal of Alloys and Compounds, 2016, 680: 60-66.
[44] Zhang Y B, Ma Q Q, Feng K K, et al. Effects of microstructure and electrochemical properties of Ti/IrO 2 -SnO 2 -Ta 2 O 5 as anodes on binder-free asymmetric supercapacitors with Ti/RuO 2 -NiO as cathodes[J]. Ceramics International, 2020, 46(11): 17640-17650.
[45] 闫镇威 , 孟惠民 , 金莹 . Ti 基氮化处理对 IrO 2 -Ta 2 O 5 涂层阳极服役性能的影响 [J]. 中国有色金属学报 , 2012, 22(12): 3495-3503.
[46] 潘建跃 , 陶自春 , 罗启富 , 等 . 含铂钛合金中间层的铱钽涂层钛阳极的研究 [J]. 材料保护 , 2003, 36(11): 46-48.
[47] 徐海清 , 胡耀红 , 陈力格 , 等 . 电解铜箔用涂层钛阳极表面结垢的去除 [J]. 电镀与涂饰 , 2015, 34(4): 201-205.
[48] 徐海清 , 胡耀红 , 陈力格 , 等 . 实际工况下电解铜箔用涂层钛阳极的失效机制 [J]. 电镀与涂饰 , 2015, 34(23): 1369-1373.
[49] 焦新贺 , 焦衡 , 徐海清 , 等 . 电解铜箔用涂层钛阳极的结垢物成因分析与维护方法 [J]. 电镀与涂饰 , 2019, 38(1): 14-19.
[50] 张招贤 . IrTa 氧化物涂层钛阳极恶化原因分析 [J]. 氯碱工业 , 2005(1): 12-16.
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备注/Memo
收稿日期： 2023-02-10 修回日期： 2023-06-06 作者简介： 张锦园（ 1999 —），女，硕士， email ： zjy13008412064@163.com * 通信作者： 刘二勇， email ： liueryong@xust.edu.cn 基金项目： 陕西省自然科学基础研究计划（ S2023-JC-ON-1976 ）；陕西省重点研发计划项目（ 2021SF-469 ）；国家自然科学基金项目（ 52175184 ）?/html>