Wang Shuai,Zhao Zhihao,Li Tianle,et al.Effect of MoS2 concentration on properties of electrodeposited Ni-P-MoS2 composite coatings[J].Plating & Finishing,2024,(12):33-39.
浓度对电沉积Ni-P-MoS2复合镀层性能的影响
- Title:
- Effect of MoS2 concentration on properties of electrodeposited Ni-P-MoS2 composite coatings
- 分类号:
- TG178
- 文献标志码:
- A
- 摘要:
- 针对工业生产中腐蚀与磨损的问题，采用电沉积的方法在Q235钢表面制备了Ni-P-MoS2复合镀层，研究了MoS2纳米颗粒的浓度对复合镀层形貌及性能的影响。研究表明，加入纳米颗粒后复合镀层表面的胞状结构增大，耐蚀性能增强，当MoS2浓度为4 g/L时阻抗值最大，为32 000 Ω·cm2，并在盐雾试验20 d后升高至58 800 Ω·cm2。随着MoS2浓度的升高，复合镀层硬度呈现先升高后降低的趋势，当浓度为4 g/L时硬度达到最高，为690.2 HV，同时MoS2的加入可以改善镀层的摩擦学性能，相较于Ni-P镀层，复合镀层的摩擦系数和磨损量分别降低了39%和55%。
- Abstract:
- Ni-P-MoS2 composite coatings was prepared on the surface of Q235 steel by electrodeposition method to solve the problems of corrosion and wear in industrial production, and the influence of the concentration of MoS 2 nanoparticles on the surface morphology and properties of the composite coating was studied. The addition of nanoparticles is shown to increase the cellular structure on the surface of the composite coating and improve corrosion resistance. When the MoS 2 concentration is 4 g/L, the impedance value reaches the maximum value of 32 000 Ω·cm 2, and increased to 58 800 Ω·cm2 after 20 days of salt spray test. With the increase of MoS 2 concentration, the hardness of composite coating shows a trend of first increasing and then decreasing. The highest hardness is 690.2 HV when the concentration is 4 g/L. And the addition of MoS 2 can improve the tribological properties of the coating. Compared with Ni-P coating, the friction coefficient and wear of composite coatings are reduced by 39% and 55%.
参考文献/References:
[1].Lelevic A, Walsh F C. Electrodeposition of Ni-P alloy coatings: A review[J]. Surface & Coatings Technology, 2019(369): 198-220.
[2].王波. 高温高压完井管柱力学分析及安全评价[D]. 成都: 西南石油大学, 2014.
[3].杜英超. 微纳米颗粒掺杂改性Ni-P复合镀层的制备及性能研究[D]. 北京: 中国科学院大学中国科学院过程工程研究所, 2021.
[4].Chinchu K S. ZrO 2-CeO2 assimilated electroless Ni-P anti-corrosion coatings[J]. Surfaces and Interfaces, 2020(21): 100704.
[5].蔡旭林, 孟为国, 肖茂华, 等. 助镀剂对化学镀Ni-P-Al2O3表面性能的影响[J]. 热加工工艺, 2019, 48(12): 84-87.
[6].林翠, 吴群英, 赵晓斌. TC4钛合金表面化学镀Ni-P-MoS2复合镀层[J]. 腐蚀与防护, 2015, 36(5): 412-418.
[7].Khaira A, Shown I, Samireddi S, et al. Mechanical and tribological characterization of deep eutectic solvent assisted electroless Ni-P- hBN coating[J]. Ceramics International, 2023, 49(1): 461-473.
[8].Safavi M S, Rasooli A. Ni-P-TiO 2 nanocomposite coatings with uniformly dispersed Ni 3Ti intermetallics: Effects of TiO2 nanoparticles concentration[J]. Surface Engineering, 2019, 35(12): 1070-1080.
[9].He Y, Wang S C, Walsh F C, et al. Self-lubricating Ni-P-MoS2 composite coatings[J]. Surface & Coatings Technology, 2016, 307: 926-934.
[10].Tajbakhsh M, Yaghobizadeh O, Farhadi Nia M. Investigation of the physical and mechanical properties of Ni-P and Ni-P-PTFE nanocomposite coatings deposited on aluminum alloy 7023[J]. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering, 2019, 233(1): 94-103.
[11].Bhattacharyya S, Mohanty D, Kumar P, et al. A corrosion and tribo-failure analysis of Ni-P-Cu coated mild steel (AISI-1040) at varied copper concentration[J]. Engineering Failure Analysis, 2023, 146: 107063.
[12].Anijdan S H M, Sabzi M, Zadeh M R, et al. The influence of pH, rotating speed and Cu content reinforcement nano-particles on wear/corrosion response of Ni-P-Cu nano-composite coatings[J]. Tribology International, 2018, 127: 108-121.
[13].刘李, 张哲晨, 靳广虎, 等. Ni-P-SiC镀层及其摩擦磨损特性研究[J]. 金属功能材料, 2023, 30(5): 123-129.
[14].Xu H, Yang Z, Li M, et al. Synthesis and properties of electroless Ni-P-nanometer diamond composite coatings[J]. Surface & Coatings Technology, 2005, 191(2): 161-165.
[15].Hsu C, Hou K, Ger M, et al. The effect of incorporated self-lubricated BN(h) particles on the tribological properties of Ni-P/BN(h) composite coatings[J]. Applied Surface Science, 2015(357): 1727-1735.
[16].Rajabalizadeh Z, Seifzadeh D, Khodayari A, et al. Corrosion protection and mechanical properties of the electroless Ni-P-MOF nanocomposite coating on AM60B magnesium alloy[J]. Journal of Magnesium and Alloys, 2022, 10(8): 2280-2295.
[17].Guo Y, Zhou X, Lee K, et al. Recent development in friction of 2D materials: from mechanisms to applications[J]. Nanotechnology, 2021, 32(31): 312002.
[18].Zhang S, Ma T, Erdemir A, et al. Tribology of two-dimensional materials: From mechanisms to modulating strategies[J]. Materials Today, 2019, 26: 67-86.
[19].Wu H, Liu F, Gong W, et al. Preparation of Ni-P-GO composite coatings and its mechanical properties[J]. Surface & Coatings Technology, 2015, 272: 25-32.
[20].刘桂芝. 基于二硫化钼的改性环氧涂层的制备及其耐腐蚀性能研究[D]. 广州: 华南理工大学, 2019.
[21].Chhowalla M, Amaratunga G. Thin films of fullerene-like MoS 2 nanoparticles with ultra-low friction and wear[J]. Nature, 2000, 407(6801): 164-167.
[22].Zhang L, Huang S. Preparation of Ni-P-Ti3C2Tx-Ce composite coating with enhanced wear resistance and electrochemical corrosion behavior on the surface of low manganese steel[J]. Surface and Coatings Technology, 2022(441): 128508.
[23].Zhang L, Huang S, Weng Y, et al. Preparation of Ni-P-Ti 3C2Tx-Ce composite coating with enhanced wear resistance and electrochemical corrosion behavior on the surface of low manganese steel[J]. Surface and Coatings Technology, 2022, 441: 128508.
[24].Zhao G. Study on the role of element Mo in improving thermal stability and corrosion resistance of amorphous Ni-P deposit[J]. Journal of Non-Crystalline Solids, 2020, 549: 120358.
相似文献/References:
[1]张冰怡,张莎莎*,姚正军,等.电沉积Ni-W纳米晶镀层制备与显微硬度研究[J].电镀与精饰,2019,(8):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
ZHANG Bingyi,ZHANG Shasha*,YAO Zhengjun,et al.Preparation and Microhardness of Electrodeposited Ni-W Nanocrystalline Coatings[J].Plating & Finishing,2019,(12):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
[2]雷同鑫,鞠 辉,张长科,等.电镀Ni-W-P合金在钻杆接头上的应用[J].电镀与精饰,2019,(10):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
LEI Tongxin,JU Hui,ZHANG Changke,et al.Application of Ni-W-P Alloy Prepared by Electroplating to Tool Joints[J].Plating & Finishing,2019,(12):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
[3]李晓峰*,孟 芳,董会超,等.电沉积法制备掺铋金属锌及其性能表征[J].电镀与精饰,2020,(1):12.[doi:10.3969/j.issn.1001-3849.2020.01.003]
LI Xiaofeng*,MENG Fang,DONG Huichao,et al.Electrodeposited Preparation of Bi-Doped Metal Zinc and Its Performance Characterization[J].Plating & Finishing,2020,(12):12.[doi:10.3969/j.issn.1001-3849.2020.01.003]
[4]张永霞,王 玫,方 华*,等.Co3O4/碳纳米管复合膜的超级电容器性能[J].电镀与精饰,2020,(2):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
ZHANG Yongxia,WANG Mei,FANG Hua*,et al.Co3O4/Carbon Nanotube Composite Film for Supercapacitor and Its Performances[J].Plating & Finishing,2020,(12):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
[5]侯珂珂,陈新华,张万强,等.电沉积法制备仿生超疏水滤网及其油水分离性能[J].电镀与精饰,2020,(4):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
HOU Keke,CHEN Xinhua,ZHANG Wanqiang,et al.Preparation of Biomimetic Superhydrophobic Filter Screen by Electrodeposition and the Oil-Water Separation Performance[J].Plating & Finishing,2020,(12):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
[6]肖成龙,梁世雍,于兆勤*.可控阵列微柱超疏水表面实验研究[J].电镀与精饰,2020,(7):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
XIAO Chenglong,LIANG Shiyong,YU Zhaoqin*.Experimental Study on Superhydrophobic Surface of Controllable Array Microcolumns[J].Plating & Finishing,2020,(12):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
[7]徐 超,王淼宇,周建波,等.电沉积Ni-Mo-Fe-La合金析氢电极的工艺研究[J].电镀与精饰,2020,(8):7.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
XU Chao,WANG Miaoyu,ZHOU Jianbo,et al.Study on Electrodeposition Process of Ni-Mo-Fe-La Alloy Hydrogen Evolution Electrode[J].Plating & Finishing,2020,(12):7.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
[8]高 辉,刘伟杰*.2A12铝合金电沉积Ni-Co-MoS2复合镀层的耐磨性能研究[J].电镀与精饰,2020,(10):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
GAO Hui,LIU Weijie*.Research on Wear Resistance of Ni-Co-MoS2 Composite Coating Electrodeposited on 2A12 Aluminium Alloy[J].Plating & Finishing,2020,(12):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
[9]王 羽,刘励昀,杜荣斌*,等.添加剂MPS、DDAC、Cl-对铜箔电沉积的影响[J].电镀与精饰,2021,(5):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
WANG Yu,LIU Liyun,DU Rongbin*,et al.Effects of Additives MPS， DDAC and Cl- on the Copper Foil[J].Plating & Finishing,2021,(12):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
[10]杨惠良*.硫酸盐镀液中紫铜电沉积Ni-Co/WC复合镀层的工艺条件优化[J].电镀与精饰,2021,(6):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]
YANG Huiliang*.Optimization of Process Conditions for Electrodeposition of Ni-Co/WC Composite Coatings on Red Copper from Sulfate Bath[J].Plating & Finishing,2021,(12):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]