QIU Xiaoyun,WANG Jiheng.Dual Sealing of Anodic Oxidation Film on Aluminum Alloy with Boiling Water and Rare Earth Salt and Mechanical Properties[J].Plating & Finishing,2022,(7):30-35.[doi:10.3969/j.issn.1001-3849.2022.07.006]
铝合金阳极氧化膜沸水-稀土盐双重封闭及力学性能研究
- Title:
- Dual Sealing of Anodic Oxidation Film on Aluminum Alloy with Boiling Water and Rare Earth Salt and Mechanical Properties
- 关键词:
- 沸水 - 稀土盐双重封闭; 阳极氧化膜; 硬度; 弹性恢复能力; 摩擦性能
- Keywords:
- dual sealing with boiling water and rare earth salt ; anodic oxidation film ; hardness ; elastic resilience ; friction property
- 分类号:
- TQ153.6
- 文献标志码:
- A
- 摘要:
- 在铝合金表面制备阳极氧化膜，并采用环保型沸水封闭与稀土盐封闭方法相结合对阳极氧化膜进行双重封闭。研究了双重封闭后阳极氧化膜的微观形貌、厚度、硬度、弹性恢复能力和摩擦性能，并与未封闭阳极氧化膜和单一封闭后阳极氧化膜比较。结果表明：单一封闭和双重封闭对阳极氧化膜的厚度影响较小，但封闭前后微观形貌明显不同。与未封闭阳极氧化膜相比，双重封闭阳极氧化膜的硬度提高了约 26% ，达到 347.5 HV ，弹性模量提高了约 27.8% ，达到 52.068 GPa ，摩擦因数和磨损失重仅为 0.37 、 2.08 mg/mm 2 。主要原因在于为双重封闭过程中发生多个反应，反应产物较好的封堵孔洞，更大程度改善阳极氧化膜的致密性，使其承载能力和抗塑性变形能力增强，从而表现出良好的力学性能。
- Abstract:
- ： Anodic oxidation film was prepared on the surface of aluminum alloy ， and it was treated by a combination of environmentally-friendly boiling water sealing and rare earth salt sealing methods. The microstructure ， thickness ， hardness ， elastic recovery ability and friction property of the anodic oxidation film after dual sealing were studied ， and compared with that of unsealed anodic oxidation film and the anodic oxidation film after single sealing. The results show that single sealing and dual sealing have little effect on the thickness of anodic oxidation film ， however the microstructure of the anodic oxidation films before and after sealing is significantly different. Compared with the unsealed anodic oxidation film ， the hardness of the anodic oxidation film after dual sealing is increased by about 26% to 347.5 HV ， the elastic modulus is increased by about 27.8% to 52.068 GPa ， and the friction factor and abrasion loss are only 0.37 and 2.08 mg/mm 2 . The main reasons are attributed to multiple reactions occurring during the dual sealing process ， the reaction products effectively seal the pores ， improve the compactness of the anodic oxidation film to a greater extent and enhance the bearing capacity and resis tance to plastic deformation ， thus e xhibit good mechanical properties.
参考文献/References:
[1] 麻彦龙 , 赵旭晗 , 杨炳元 , 等 . 铝合金阳极氧化膜封闭技术发展趋势 [J]. 重庆理工大学学报 : 自然科学 , 2020, 34(9): 131-140.
[2] Lee W, Park S J. Porous anodic aluminum oxidation: anodization and templated synthesis of functional nanostructures[J]. Chemical Reviews, 2014, 114(15): 7487-7556.
[3] Yu Y D, Ge H L, Wei G Y, et al. 2024 aluminum oxidation films prepared by the innovative and environmental friendly oxidation technology[J]. Surface Review and Letters, 2020, 27(12): 2050020.
[4] 张培 , 赵旭辉 , 唐聿明 , 等 . 铝阳极氧化膜的微观结构及沸水封闭处理对膜层显微硬度的影响 [J]. 表面技术 , 2013, 42(5): 45-47.
[5] 成映星 , 付明 , 周玉龙 , 等 . 铝合金着黑色阳极氧化膜变色故障的分析和处理 [J]. 电镀与涂饰 , 2016, 35(8): 419-421.
[6] 危 灿 . 铝及铝合金阳极氧化膜的封闭方法 [J]. 广东化工 , 2015, 42(3): 82-83.
[7] Zeng J M, Kim Y H, Chen Y F. Effect of praseodymium salt on properties of anodic aluminum oxidation films[J]. Advanced Materials Research, 2011(399-401): 847-850.
[8] 郑勇宏 . 铝合金阳极化膜双重封闭工艺试验与分析 [J]. 航空维修与工程 , 2018, 12: 66-67.
[9] 邱小云 , 王冀恒 . 双重封闭对铝锂合金阳极氧化膜耐蚀性的影响 . 兵器材料科学与工程 , 2021, 44(5): 120-125.
[10] 陈朝英 , 魏晓伟 , 王建 , 等 . 温度梯度降温对铝合金阳极氧化膜性能的影响 [J]. 腐蚀与防护 , 2012,33(3): 244-246.
[11] 陈高红 , 胡远森 , 于美 , 等 . 硫酸阳极化对 2E12 铝合金力学性能的影响 [J]. 中国腐蚀与防护学报 , 2018, 38(6): 579-586.
[12] 卢洁琴 . 铝合金环保阳极氧化膜的制备及其力学性能研究 [D]. 杭州 : 中国计量大学 , 2017.
[13] 丁小理 , 邓汝荣 , 罗杰 , 等 . 固溶时效处理对 6013 铝合金型材组织和性能的影响 [J]. 轻合金加工技术 , 2020, 48(4): 47-51.
[14] 李峰 , 张建周 , 马慧媛 , 等 . 稀土盐对铝合金硼硫酸阳极氧化膜层性能的影响 [J]. 表面技术 , 2014, 43(6): 95-99.
[15] 谭孟曦 . 利用纳米压痕加载曲线计算硬度 - 压入深度关系及弹性模量 [J]. 金属学报 , 2005, 41(10): 1020-1024.
[16] 王晓宇 , 王金良 , 彭洪勇 . 有限元分析薄膜 / 基底在纳米压痕过程中的力学性能 [J]. 人工晶体学报 , 2014, 43(2): 327-332.
[17] 常超 , 高亮亮 , 叶启华 . 残余应力对 Oliver-Pharr 方法测量弹性模量的影响 [J]. 理化检验 : 物理分册 , 2020, 56(10): 1-4.
[18] 张志杰 . 材料力学性能的压入试验方法与应用 [D]. 成都 : 西南交通大学 , 2019.
[19] 郭彦飞 , 张鲲 , 刘莉 , 等 . 溶胶 - 凝胶封孔处理对铝合金阳极氧化膜耐蚀及耐磨性能的影响 [J]. 材料热处理学报 , 2014, 35(9): 182-187.
[20] 赵红锦 . 7075 铝合金表面阳极氧化膜的制备及其摩擦学性能的研 究 [ D]. 青岛 : 青岛理工大学 , 2019.
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备注/Memo
收稿日期： 2021-12-07 修回日期： 2022-03-14 作者简介： 邱小云（ 1977 —），江西南昌人，硕士，副教授， Email ： teacher_20@126.com 基金项目： 江苏省高校品牌专业建设工程资助项目（ PPZY2015C232 ）、江苏省高等职业教育高水平专业群建设项目（苏教职函〔 2021 〕 1 号： 1-10 ）