Zhang Lu,Zhang Zhongquan,Yu Yundan,et al.Electrodeposition of CoFe/ZrO 2 composite films and their oxygen evolution performance[J].Plating & Finishing,2024,(1):9-14.[doi:10.3969/j.issn.1001-3849.2024.01.002]
CoFe/ZrO2复合膜的电沉积及其析氧性能研究
- Title:
- Electrodeposition of CoFe/ZrO 2 composite films and their oxygen evolution performance
- Keywords:
- electrodeposition ; composite films ; bath temperature ; oxygen evolution reaction
- 分类号:
- TQ153.2
- 文献标志码:
- A
- 摘要:
- 为降低电解水阳极析氧反应的过电位，采用电化学沉积技术制备了 CoFe/ZrO 2 复合膜。在碱性介质中，该复合膜表现出了优异的析氧反应（ OER ）活性，在电流密度 10 mA/cm?#1602下过电势仅为 1.56 V ，远低于 CoFe （ 1.694 V ），这主要是由于 CoFe/ZrO 2 复合膜具有足够暴露的活性位点和较高的电子转移能力。进一步的研究表明， CoFe/ZrO 2 复合膜可以在 1.58 V 过电位下稳定运行 12 h ，经 2000 圈循环伏安测试后， OER 活性曲线未存在明显差别，显示 CoFe/ZrO 2 复合膜具有良好稳定性。本文工作可为探索经济高效的 OER 催化电极膜材料开辟一条新途径，替代贵金属在可再生能源转换中应用。
- Abstract:
- ： In order to reduce the overpotential of anodic oxygen evolution reaction during water electrolysis ， CoFe/ZrO 2 composite films were prepared using electrochemical deposition technology. The composite films exhibit excellent oxygen evolution reaction （ OER ） activity in alkaline media ， with an overpotential of only 1.56 V at a current density of 10 mA/cm 2 ， which is significantly lower than that of CoFe （ 1.694 V ） . This is mainly due to the sufficient exposed active sites and high electron transfer capacity of the CoFe/ZrO 2 composite film. Further studies have shown that the CoFe/ZrO 2 composite membrane can operate stably at an overpotential of 1.58 V for 12 h.After 2000 cycles of cyclic voltammetry testing ， there is no significant difference in the OER activity curves ， indicating that the CoFe/ZrO 2 composite membrane has good stability. The work may open up a new way to explore cost-effective OER catalytic electrode membrane materials to replace precious metals in the application of renewable energy conversion.
参考文献/References:
[1] Li G Z, Sun T, Niu H J, et al. Triple interface optimization of Ru-based electrocatalyst with enhanced activity and stability for hydrogen evolution reaction[J]. Advanced Functional Materials, 2023, 2212514.
[2] Wang X, Mao Z L, Mao X, et al. Dual integrating oxygen and sulphur on surface of CoTe nanorods triggers enhanced oxygen evolution reaction[J]. Advanced Science, 2023, 2206204.
[3] Zhang Y W, Zhang X F, Li Y T, et al. FeCo alloy/N, S co-doped carbon aerogel derived from directional-casting cellulose nanofibers for rechargeable liquid flow and flexible Zn-air batteries[J/OL]. Nano Research, 2023, https://link.springer.com/article/10.1007/s12274-023-5409-4
[4] Kuo D Y, Paik H, Kloppenburg J, et al. Measurements of oxygen electroadsorption energies and oxygen evolution reaction on RuO 2 (110): A discussion of the sabatier principle and its role in electrocatalysis[J]. Journal of the American Chemical Society, 2018, 140(50): 17597-17605.
[5] Kim M, Kang S B, Fundamental analysis for active phase of rutile-based IrO2 catalyst: Comparison study of CH 4 oxidation on IrO 2 (100) and IrO 2 (110) [J]. Applied Surface Science, 2022, 605: 154827.
[6] Meng X, Li Z, Liu Y Y, et al. Enabling unassisted solar water splitting with concurrent high efficiency and stability by robust earth-abundant bifunctional electrocatalysts[J]. Nano Energy, 2023, 109: 108296.
[7] Lee D, Moru S, Reddy K P, et al. Bimetallic Cu-Ni core-shell nanoparticles anchored N-doped reduced graphene oxide as a high-performance bifunctional electrocatalyst for alkaline water splitting[J]. Applied Surface Science, 2023, 622: 156928.
[8] Gaur A, John J M, Pundir V, et al. Electronegativity-induced valence state augmentation of Ni and Co through electronic redistribution between Co-Ni 3 N/CeF 3 interfaces for oxygen evolution reaction[J]. ACS Applied Energy Materials, 2023, 6(3): 1763 – 1770.
[9] Liu R B, Song T. S, Xue H, et al. Surface reconstruction of iron – cobalt – nickel phosphides to achieve high-current-density water oxidation performance[J]. ACS Applied Energy Materials, 2023, 6(2): 692-701.
[10] Ogawa S, Nakayama K, Katayama M, et al. Highly durable bifunctional gas diffusion electrodes fabricated with melilite-type Fe/Co/Ni-mixed oxide electrocatalysts[J]. ACS Applied Energy Materials, 2022, 5(12), 15502-15509.
[11] Xie S, Jin H C, Wang C, et al. A comparison study on single metal atoms (Fe, Co, Ni) within nitrogen-doped graphene for oxygen electrocatalysis and rechargeable Zn-air batteries[J/OL]. Chinese Chemical Letters, 2022, https://doi.org/10.1016/j.cclet.2022.07.024
[12] Moloudi M, Noori A, Rahmanifar M S, et al. Layered double hydroxide templated synthesis of amorphous NiCoFeB as a multifunctional electrocatalyst for overall water splitting and rechargeable zinc – air batteries[J]. Advanced Energy Materials, 2023, 13(4), 2203002.
[13] Naqvi S T R, Rasheed T, Majeed S, et al. Development of nitrogen doped carbon dots modified CuCo alloy nanoparticles for potential electrocatalytic water splitting[J]. Journal of Molecular Liquids, 2020, 309: 113111.
[14] Li N, Liu X. A comparison of the catalytic efficiency of copper-based bimetallic nanoparticles in the click reactions[J]. Journal of Chemical Research. 2020, 44(9-10):566-570.
[15] Wei Y, Zheng M B, Zhu W, et al. Preparation of hierarchical hollow CoFe Prussian blue analogues and its heat-treatment derivatives for the electrocatalyst of oxygen evolution reaction[J]. Journal of Colloid and Interface Science, 2023, 631: 8-16.
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备注/Memo
收稿日期： 2023-02-27 修回日期： 2023-03-21 作者简介： 张璐（ 1995 ―），男，硕士研究生， email ： zl154109739@163.com * 通信作者： 卫国英， email ： guoyingwei@cjlu.edu.cn 基金项目： 国家自然科学基金资助项目（ 52171083 ）