Yang Dan,Sun Cuiling,Lin Xiuzhou,et al.Effect of modification methods on ZIF-8 film growth behaviors on aluminum alloy[J].Plating & Finishing,2023,(1):16-22.[doi:10.3969/j.issn.1001-3849.2023.01.003]
铝合金表面改性对ZIF-8膜层生长行为的影响
- Title:
- Effect of modification methods on ZIF-8 film growth behaviors on aluminum alloy
- Keywords:
- aluminum alloy ; dopamine ; hydrotalcite ; zeolitic imidazolate framework
- 分类号:
- TQ174.4
- 文献标志码:
- A
- 摘要:
- 采用多巴胺改性和预制水滑石（ LDH ）模板两种不同改性方式对铝合金改性，研究了改性方式对其表面金属有机骨架膜层（ MOF ）生长性能的影响。通过微观形貌、相组成及能谱对膜层组织结构进行了表征，并通过电化学阻抗和动电位极化曲线探究膜层的耐蚀性。结果表明：多巴胺改性后的铝合金表面难以形成连续的沸石咪唑骨架膜层（ ZIF-8 ）膜层，而采用预制 LDH 模板的方式可在铝合金表面制备连续致密的 ZIF-8 膜，并且采用预制 LDH 模板得到的膜层其低频阻抗模值较铝合金而言提升了 1 个数量级，达到 8.79×10 4 Ω ·cm 2 ，可对铝合金起到较好的防护性能。
- Abstract:
- ： The aluminum alloy was modified by two different methods ： dopamine modification and prefabricated hydrotalcite （ LDH ） template ， and the effect of modification methods on the growth behaviors of metal organic framework film （ MOF ） was studied. The microstructure of the film was characterized by micro morphology ， phase composition and energy spectrum ， and the corrosion resistance of the film was investigated by electrochemical impedance and potentiodynamic polarization curve. The results show that it is difficult to form a continuous zeolite imidazole framework film （ ZIF-8 ） on the surface of aluminum alloy modified by dopamine ， but a continuous and dense ZIF-8 film can be prepared on the surface of aluminum alloy by prefabricated LDH template ， and the low-frequency impedance modulus of the film obtained by prefabricated LDH template is one order of magnitude higher than that of aluminum alloy ， reaching 8.79×10 4 Ω ·cm 2 ， which can play a good protective performance on aluminum alloy.
参考文献/References:
[1] 林钢 , 林慧国 , 赵玉涛 . 铝合金应用手册 [M]. 北京 : 机械工业出版社 , 2006.
[2] 杨冠华 , 王洪涛 , 张鲲 , 等 . 施镀工艺对铝合金化学镀镍的影响 [J]. 材料保护 , 2020, 53(11): 55-61, 93.
[3] 赵华星 , 孙晓峰 , 宋巍 , 等 . 微弧氧化技术在铝合金腐蚀防护中的应用研究与发展 [J]. 材料导报 , 2021, 35(21): 21236-21242.
[4] 郭蓓 , 李冬冬 , 束俊杰 , 等 . 铝合金表面化学转化膜制备技术的研究进展 [J]. 材料保护 , 2021, 54(9): 106-113.
[5] 李莹 , 林雨 , 孙晓英 , 等 . MOF 复合材料的制备及应用研究进展 [J]. 化工新型材料 , 2018, 46(3): 6-9, 13.
[6] 秦茜 , 孙玉绣 , 王乃鑫 , 等 . 表面修饰在 MOF 薄膜制备中的应用 [J]. 化工进展 , 2017, 36(4): 1306-1315.
[7] 丁锐 . 纳米 ZIF-8 的尺度调控及其混合基质膜的 CO 2 分离性能 [D]. 大连 : 大连理工大学 , 2018.
[8] 康杰 . ZIF-8 的制备及其性能研究 [D]. 桂林 : 广西师范大学 , 2021.
[9] Li J, Yan M D, Yan Y, et al. Recent advances of metal-organic frameworks in corrosion protection: from synthesis to applica tions[J]. Chemical Engineering Journal, 2021, 430: 132823.
[10] 陈怀银 . 金属有机骨架材料在海洋腐蚀检测与防护中的应用研究 [D]. 北京 : 中国科学院大学 ( 中国科学院海洋研究所 ), 2019.
[11] Seyed M L, Hossain Y, Mohammad M, et al. Application of nanoporous cobalt-based ZIF-67 metal-organic framework (MOF) for construction of an epoxy-composite coating with superior anti-corrosion properties[J]. Corrosion Science, 2021, 178: 109099.
[12] Duan S, Dou B J, Lin X Z, et al. Influence of active nanofiller ZIF-8 metal-organic framework (MOF) by microemulsion method on anticorrosion of epoxy coatings[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 624: 126836.
[13] Dangwal S, Ronte A, Kim S J, et al. ZIF-8 membranes supported on silicalite-seeded substrates for propylene/propane separation[J]. Journal of Membrane Science, 2021, 626: 119165.
[14] Ma K, Wang N X , Wang C C, et al. Freezing assisted in situ growth of nano-confined ZIF-8 composite membrane for dye removal from water[J]. Journal of Membrane Science, 2021, 632: 119352.
[15] 张玉圣 , 王友彬 , 李纯民 , 等 . 6061 铝合金表面 ZnAl-LDHs 层的制备及其耐腐蚀性能 [J]. 金属学报 , 2018, 54(10): 1417-1427.
[16] Lai, Zhi P, Wang, et al. ZIF-8 membranes with improved reproducibility fabricated from sputter-coated ZnO/alumina supports[J]. Chemical Engineering Science, 2016, 141(17): 119-124.
[17] Xu T, Zhao Y, Hu J M, et al. Composite nanocontainers synthesized by in-situ growth of metal organic frameworks on layered double hydroxides having both passive and active protecting capabilities[J]. Progress in Organic Coatings, 2022, 164: 106695.
[18] Hiroki K, Yuta N , Kousuke Y, et al. Surfactant-assisted synthesis of nanocrystalline zeolitic imidazolate framework 8 and 67 for adsorptive removal of perfluorooctane sulfonate from aqueous solution[J]. Catalysis Today, 2020, 352: 220-226.
[19] 陈凌云 . 基于 ZIF-8 新型复合材料的制备、表征及吸附性能研究 [D]. 新乡 : 河南师范大学 , 2015.
[20] Jyh J B , Jit K L , Eng P N, et al. Synthesis and size control of zeolitic imidazolate framework-8 (ZIF-8): From the perspective of reaction kinetics and thermodynamics of nucleation[J]. Materials Chemistry and Physics, 2018, 216: 393-401.
相似文献/References:
[1]王艳伟.填充工序对铝合金壳体零件铬酸阳极化色差的影响[J].电镀与精饰,2019,(7):40.[doi:10.3969/j.issn.1001-3849.2019.07.009]
WANG Yanwei.Influence of Filling Process on Color Difference of Aluminum Alloy Shell after Chromic Acid Anodization[J].Plating & Finishing,2019,(1):40.[doi:10.3969/j.issn.1001-3849.2019.07.009]
[2]黄碧芳*,李远会,王 丽,等.铝合金磷钼酸亚铁转化体系工艺研究[J].电镀与精饰,2019,(9):29.[doi:10.3969/j.issn.1001-3849.2019.09.006]
HUANG Bifang*,LI Yuanhui,WANG Li,et al.Study on the Conversion Process of Ferrous Phosphomolybdate on Aluminum Alloy[J].Plating & Finishing,2019,(1):29.[doi:10.3969/j.issn.1001-3849.2019.09.006]
[3]元 泉,邱 媛*,刘 洋,等.铝合金漆层与氧化层激光清洗应用研究[J].电镀与精饰,2019,(12):25.[doi:10.3969/j.issn.1001-3849.2019.12.006]
YUAN Quan,QIU Yuan#,LIU Yang,et al.Research on Laser Cleaning Application for Coating and Oxide Layer of Aluminum Alloy[J].Plating & Finishing,2019,(1):25.[doi:10.3969/j.issn.1001-3849.2019.12.006]
[4]季 伟,孟繁东,潘科宇,等.铝合金表面油污清洗剂的制备及其腐蚀性研究[J].电镀与精饰,2021,(2):38.[doi:10.3969/j.issn.1001-3849.2021.02.0080]
JI Wei,MENG Fandong,PAN Keyu,et al.季 伟1，孟繁东1，潘科宇1，王文军1，潘明华1，韩怡秋2，邵明亮2，刘 东3，周 勇3*[J].Plating & Finishing,2021,(1):38.[doi:10.3969/j.issn.1001-3849.2021.02.0080]
[5]张子聪,郝建军*,赵荣兴.铝合金复合石墨烯薄膜的制备及腐蚀性能研究[J].电镀与精饰,2021,(7):15.[doi:10.3969/j.issn.1001-3849.2021.07.003]
ZHANG Zicong,HAO Jianjun*,ZHAO Rongxing.Study on Preparation and Corrosion Performance of Aluminum Alloy Composite Graphene Film[J].Plating & Finishing,2021,(1):15.[doi:10.3969/j.issn.1001-3849.2021.07.003]
[6]刘奋照*.几种铝合金材料在汽车防冻液中的腐蚀行为[J].电镀与精饰,2021,(9):59.[doi:10.3969/j.issn.1001-3849.2021.09.010]
LIU Fenzhao*.Corrosion Behavior of Several Aluminum Alloy in Automobile Antifreeze[J].Plating & Finishing,2021,(1):59.[doi:10.3969/j.issn.1001-3849.2021.09.010]
[7]刘 静,马小昭,王帅星.绝缘保护用铬酸阳极氧化工艺研究[J].电镀与精饰,2022,(6):41.[doi:10.3969/j.issn.1001-3849.2022.06.009]
LIU Jing,MA Xiaozhao,WANG Shuaixing.Research on Chromic Acid Anodizing Technique for Insulation Protection[J].Plating & Finishing,2022,(1):41.[doi:10.3969/j.issn.1001-3849.2022.06.009]
[8]李志强,魏红阳,陈东初*,等.电源参数对铝合金表面复合氧化膜的多彩电解着色的影响规律研究[J].电镀与精饰,2022,(6):52.[doi:10.3969/j.issn.1001-3849.2022.06.011]
LI Zhiqiang,WEI Hongyang,CHEN Dongchu*,et al.Effects of Power Parameters on Electrolytic Colouring of Colorful Composite Oxide Film on Aluminum Alloy Surface[J].Plating & Finishing,2022,(1):52.[doi:10.3969/j.issn.1001-3849.2022.06.011]
[9]李廷取 *,刘祥玲,刘文异. 不同占空比对6061铝合金微弧氧化着色及性能的影响研究 [J].电镀与精饰,2022,(9):20.[doi:10.3969/j.issn.1001-3849.2022.09.004]
LI Tingqu *,LIU Xiangling,LIU Wenyi.Study on Microarc Oxidation Coloring and Properties of 6061 Aluminum Alloy with Different Duty Ratios[J].Plating & Finishing,2022,(1):20.[doi:10.3969/j.issn.1001-3849.2022.09.004]
[10]刘巧娣*,邓国军. 硫酸阳极化膜层出现白色粉末问题原因分析 [J].电镀与精饰,2022,(10):88.[doi:10.3969/j.issn.1001-3849.2022.10.015]
LIU Qiaodi*,DENG Guojun.Cause Analysis of White Powder in Sulfuric Acid Anodized Film[J].Plating & Finishing,2022,(1):88.[doi:10.3969/j.issn.1001-3849.2022.10.015]
备注/Memo
收稿日期： 2022-05-18 修回日期： 2022-06-13 作者简介： 杨丹（ 1997 ―），女，硕士研究生，研究方向：从事表面工程技术， email ： yangdanbq@163.com * 通信作者： 罗松， email ： stravel@126.com 基金项目： 国家自然科学基金（ No. 51901146 ），四川省科技厅（ No. 2020JDRC0098 ， 2021YFG0246 ）?/html>