Shen Li *,??an Jie.Effect of yttrium nitrate on properties of Co-W-P alloy coatings electrodeposited on brass matrix[J].Plating & Finishing,2024,(6):55-62.[doi:10.3969/j.issn.1001-3849.2024.06.008]
硝酸钇对黄铜基体电沉积Co-W-P合金镀层性能的影响
- Title:
- Effect of yttrium nitrate on properties of Co-W-P alloy coatings electrodeposited on brass matrix
- 关键词:
- Co-W-P 合金镀层; 电沉积; 硝酸钇; 抗磨损性能; 抗划伤性能
- Keywords:
- Co-W-P alloy coating ; electrodeposition ; yttrium nitrate ; wear resistance ; scratch resistance
- 分类号:
- TQ153
- 文献标志码:
- A
- 摘要:
- 选用硝酸钇作为添加剂加到镀液中，研究了硝酸钇添加量对黄铜基体上电沉积 Co-W-P 合金镀层的外观、微观形貌、组织结构、硬度、抗磨损性能与抗划伤性能的影响。结果表明：改变硝酸钇添加量对 Co-W-P 合金镀层的外观、覆盖能力、衍射峰位置以及择优取向无明显影响，但添加适量硝酸钇使 Co-W-P 合金镀层中孔洞数量减少，表面致密性逐步改善，硬度增大，抗磨损性能与抗划伤性能明显提高。当硝酸钇的添加量为 3 g/L ，电沉积的 Co-W-P 合金镀层表面平整且致密，呈现（ 200 ）晶面择优取向，硬度达到 536.8 HV ，磨损量仅为 4.6 mg/cm 2 并且表面磨损程度轻，表现出良好的抗磨损性能与抗划伤性能。
- Abstract:
- ： Yttrium nitrate was added to the plating solution as an additive ， and the effect of the addition amount of yttrium nitrate on the appearance ， microstructure ， hardness ， wear resistance and scratch resistance of the Co-W-P alloy coatings electrodeposited on brass matrix was studied. The results show that changing the addition amount of yttrium nitrate has no obvious effect on the appearance ， covering ability ， position of diffraction peak and preferred orientation of Co-W-P alloy coatings ， but adding appropriate amount of yttrium nitrate can reduce the number of holes in Co-W-P alloy coating ， improve the surface compactness gradually ， increase the hardness and improve the wear resistance and scratch resistance obviously. The Co-W-P alloy coating electrodeposited with yttrium nitrate 3 g/L has flat and dense surface ， showing a preferred orientation of （ 200 ） crystal plane. The hardness reaches 536.8 HV ， the wear amount is only 4.6 mg/cm 2 and the surface wear degree is light ， showing good wear resistance and scratch resistance.
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备注/Memo
收稿日期： 2024-01-16 修回日期： 2024-03-04 * 通信作者： 沈丽（ 1979 —），副教授，主要研究方向：机械设计与制造、表面工程等， email ： Edu_shen006@126.com 基金项目： 河南省自然科学基金面上项目（ 182300410200 ）?/html>