[1]刘季润,魏寅莎,欧阳义波,等.doi: 10.3969/j.issn.1001-3849.2025.07.005铝表面一步法电沉积制备超疏水涂层及防腐蚀研究[J].电镀与精饰,2025,(07):29-36.
　Liu Jirun,Wei Yinsha,Ouyang Yibo,et al.Preparation of superhydrophobic coating and its corrosion resistance on aluminum surface by one-step electrodeposition[J].Plating & Finishing,2025,(07):29-36.
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doi: 10.3969/j.issn.1001-3849.2025.07.005铝表面一步法电沉积制备超疏水涂层及防腐蚀研究()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2025年07
页码:
29-36
栏目:
出版日期:
2025-07-31

文章信息/Info

Title:
Preparation of superhydrophobic coating and its corrosion resistance on aluminum surface by one-step electrodeposition
作者:
刘季润1; 魏寅莎2; 欧阳义波3; 李如友1; 李腾飞1; 候吉浩1; 刘海强1; 邱 日1*
(1. 山东科技大学 安全与环境工程学院,山东 青岛 266590; 2. 哈尔滨工程大学 材料科学与化学工程学院,黑龙江 哈尔滨 150001; 3. 大连理工大学 材料科学与工程学院,辽宁 大连 116024)
Author(s):
Liu Jirun1;  Wei Yinsha 2 ;  Ouyang Yibo3;  Li Ruyou1 ;  Li Tengfei1
Hou Jihao 1, Liu Haiqiang1, Qiu Ri1* 1.College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qing Dao 266590, China; 2. School of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China; 3. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
关键词:
耐蚀性能; 电沉积; 超疏水
Keywords:
corrosion resistance;  electrodeposition;  superhydrophobic
分类号:
TG174
文献标志码:
A
摘要:
针对铝金属在应用中广泛存在的易受腐蚀问题，采用一步电沉积法在铝表面制备了超疏水涂层，研究了该涂层对铝耐腐蚀性能的影响。结果表明：在一步电沉积法的条件下，所制备的栗壳状超疏水结构可以显著提高铝金属的耐蚀性能。该涂层主要由肉豆蔻酸钙构成，呈现出独特的栗壳状微观结构，水滴在其表面的接触角高达156°，显示出优异的超疏水性能。在3.5 wt.% NaCl溶液中浸泡168 h后，超疏水涂层的低频阻抗|Z|0.01Hz仍保持3.16×105 Ω·cm2，缓蚀效率高达96.58%，相较于裸铝显著提升了耐腐蚀性能。除此之外，通过跟踪盐粒潮解-干燥过程，所制备的超疏水表面在大气环境中表现出了优异的耐蚀性能，为铝金属的防腐提供了新的途径。
Abstract:
To address the ubiquitous corrosion issue of aluminum and mitigate its detrimental effects on materials durability and environmental sustainability, we have developed a one-step electrodeposition method to fabricate superhydrophobic coating on aluminum surface. The as-prepared coating exhibits a unique chestnut-like micro-nano structure composed primarily of calcium myristate, with a static contact angle as high as 156°, demonstrating excellent superhydrophobicity. After soaking in a 3.5 wt.% NaCl solution for 168 h, the |Z|0.01Hz of the superhydrophobic coating reached 3.16×105 Ω cm2, with a corrosion inhibition efficiency of 96.58%. Compared with the bare aluminum substrate sample, it has a significant improvement in corrosion resistance. In addition, by the deliquesce-drying process, the prepared superhydrophobic samples also exhibited excellent corrosion resistance in atmospheric environments, providing a new effective way for the corrosion prevention of aluminum

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更新日期/Last Update: 2025-07-08