[1]李晓峰*,孟 芳,董会超,等.电沉积法制备掺铋金属锌及其性能表征[J].电镀与精饰,2020,(1):12-17.[doi:10.3969/j.issn.1001-3849.2020.01.003]
　LI Xiaofeng*,MENG Fang,DONG Huichao,et al.Electrodeposited Preparation of Bi-Doped Metal Zinc and Its Performance Characterization[J].Plating & Finishing,2020,(1):12-17.[doi:10.3969/j.issn.1001-3849.2020.01.003]
点击复制

电沉积法制备掺铋金属锌及其性能表征()

《电镀与精饰》[ISSN:1001-3849/CN:12-1096/TG]

卷:
期数:
2020年1
页码:
12-17
栏目:
出版日期:
2020-01-15

文章信息/Info

Title:
Electrodeposited Preparation of Bi-Doped Metal Zinc and Its Performance Characterization
作者:
李晓峰1*; 孟 芳2; 董会超1; 宋延华1; 古亚丽1
1. 郑州轻工业大学材料与化工学院，河南 郑州 450001； 2. 河南国能电池有限公司，河南 郑州 451450
Author(s):
LI Xiaofeng1*;  MENG Fang2;  DONG Huichao1;  SONG Yanhua1;  GU Yali1
1. School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China; 2. Henan Guoneng Battery Co. Ltd., Zhengzhou 451450, China
关键词:
电沉积; 金属锌电极; 铋掺杂
Keywords:
electrodeposition;  metal zinc electrode;  Bi?doped
DOI:
10.3969/j.issn.1001-3849.2020.01.003
文献标志码:
A
摘要:
以铜片为基体，分别在酸性或碱性镀液中电沉积得到掺铋的金属锌电极。采用X射线衍射（XRD）、电感耦合等离子光谱（ICP）和扫描电子显微镜（SEM）等测试手段对制备的材料进行了表征。结果表明，在碱性镀液中添加Bi离子并不能从根本上改变金属锌疏松的树枝状沉积形态，随着镀液中Bi含量的增加，沉积层中的金属铋含量几乎不发生变化；而在酸性镀液中添加Bi离子后，金属锌由致密的树枝状沉积改变为颗粒状沉积，且随着镀液中Bi含量的增加，金属铋在锌沉积层中的含量线性增加。后者能够在一定程度上提高二次锌负极在1 mol·L-1 ZnSO4溶液中的放电容量并改善其循环性能，这可能得益于金属锌结晶形态的改变。
Abstract:
Bismuth-doped metal zinc electrode was prepared on the copper substrate by electrodeposition in acidic or alkaline bath, respectively. X-ray diffraction (XRD), inductively coupled plasma spectroscopy (ICP) and scanning electron microscope (SEM) tests were used to characterize the performance of the prepared materials. The results show that the dendritic deposition morphology of loose zinc metal can not be changed fundamentally by the addition of Bi ions into alkaline bath, and the Bi content in the deposit layer hardly changes with the increase of Bi content in the bath. On the contrary, the dendritic deposition morphology of dense metal zinc changes to granular deposit with the addition of Bi ions in acidic bath, and the Bi content in the deposit layer increases linearly with the increase of Bi content in the bath. The latter can improve the discharge capacity and cycle performance of secondary zinc anode in 1 mol·L-1 ZnSO4 solution to a certain extent, which may be due to the crystalline morphology change of zinc metal.

参考文献/References:

[1] 李思振, 孙岚, 胡融刚, 等. 锌铋合金电极在溶胶电解液中的电化学行为[J]. 物理化学学报, 2009, 25(8): 1635-1640.
[2] 王志林. 强碱溶液中铋、铟对锌电极电化学行为的影响[D]. 厦门大学化学系, 2007.
[3] 闫洪. 热浸镀涂层的耐蚀性和应用[J]. 化工腐蚀与防护, 1996(2): 49-52.
[4] Ming J, Guo J, Xia C, et al. Zinc-ion batteries: materials, mechanisms, and applications [J]. Materials Science & Engineering R, 2019, 135: 58-84.
[5] Sun K E K, Hoang T K A, Doan N L, et al. Suppression of dendrite formation and corrosion on zinc anode of secondary aqueous batteries [J]. Applied Materials & Interfaces, 2017, 9: 9681-9687.
[6] 吴涛, 刘志宏, 张多默. 无汞碱锰电池负极材料缓蚀剂的研究[J]. 电池, 2003, 33(6): 373-374.

相似文献/References:

[1]张冰怡,张莎莎*,姚正军,等.电沉积Ni-W纳米晶镀层制备与显微硬度研究[J].电镀与精饰,2019,(8):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
　ZHANG Bingyi,ZHANG Shasha*,YAO Zhengjun,et al.Preparation and Microhardness of Electrodeposited Ni-W Nanocrystalline Coatings[J].Plating & Finishing,2019,(1):20.[doi:10.3969/j.issn.1001-3849.2019.08.005]
[2]雷同鑫,鞠 辉,张长科,等.电镀Ni-W-P合金在钻杆接头上的应用[J].电镀与精饰,2019,(10):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
　LEI Tongxin,JU Hui,ZHANG Changke,et al.Application of Ni-W-P Alloy Prepared by Electroplating to Tool Joints[J].Plating & Finishing,2019,(1):38.[doi:10.3969/j.issn.1001-3849.2019.10.009]
[3]张永霞,王 玫,方 华*,等.Co3O4/碳纳米管复合膜的超级电容器性能[J].电镀与精饰,2020,(2):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
　ZHANG Yongxia,WANG Mei,FANG Hua*,et al.Co3O4/Carbon Nanotube Composite Film for Supercapacitor and Its Performances[J].Plating & Finishing,2020,(1):1.[doi:10.3969/j.issn.1001-3849.2020.02.001]
[4]侯珂珂,陈新华,张万强,等.电沉积法制备仿生超疏水滤网及其油水分离性能[J].电镀与精饰,2020,(4):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
　HOU Keke,CHEN Xinhua,ZHANG Wanqiang,et al.Preparation of Biomimetic Superhydrophobic Filter Screen by Electrodeposition and the Oil-Water Separation Performance[J].Plating & Finishing,2020,(1):1.[doi:10.3969/j.issn.1001-3849.2020.04.0010]
[5]徐 超,王淼宇,周建波,等.电沉积Ni-Mo-Fe-La合金析氢电极的工艺研究[J].电镀与精饰,2020,(8):7.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
　XU Chao,WANG Miaoyu,ZHOU Jianbo,et al.Study on Electrodeposition Process of Ni-Mo-Fe-La Alloy Hydrogen Evolution Electrode[J].Plating & Finishing,2020,(1):7.[doi:10.3969/j.issn.1001-3849.2020.08.0020]
[6]肖成龙,梁世雍,于兆勤*.可控阵列微柱超疏水表面实验研究[J].电镀与精饰,2020,(7):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
　XIAO Chenglong,LIANG Shiyong,YU Zhaoqin*.Experimental Study on Superhydrophobic Surface of Controllable Array Microcolumns[J].Plating & Finishing,2020,(1):27.[doi:10.3969/j.issn.1001-3849.2020.07.0060]
[7]高 辉,刘伟杰*.2A12铝合金电沉积Ni-Co-MoS2复合镀层的耐磨性能研究[J].电镀与精饰,2020,(10):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
　GAO Hui,LIU Weijie*.Research on Wear Resistance of Ni-Co-MoS2 Composite Coating Electrodeposited on 2A12 Aluminium Alloy[J].Plating & Finishing,2020,(1):1.[doi:10.3969/j.issn.1001-3849.2020.10.0010]
[8]姚伦芳,罗雪芳,刘定富*.热处理温度对电沉积Ni-W-B合金镀层性能的影响[J].电镀与精饰,2022,(9):93.[doi:10.3969/j.issn.1001-3849.2022.09.016]
　YAO Lunfang,LUO Xuefang,LIU Dingfu*.Effect of Heat Treatment on the Coating Properties of Electrodeposited Ni-W-B Alloy[J].Plating & Finishing,2022,(1):93.[doi:10.3969/j.issn.1001-3849.2022.09.016]
[9]王 羽,刘励昀,杜荣斌*,等.添加剂MPS、DDAC、Cl-对铜箔电沉积的影响[J].电镀与精饰,2021,(5):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
　WANG Yu,LIU Liyun,DU Rongbin*,et al.Effects of Additives MPS， DDAC and Cl- on the Copper Foil[J].Plating & Finishing,2021,(1):1.[doi:10.3969/j.issn.1001-3849.2021.05.001]
[10]杨惠良*.硫酸盐镀液中紫铜电沉积Ni-Co/WC复合镀层的工艺条件优化[J].电镀与精饰,2021,(6):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]
　YANG Huiliang*.Optimization of Process Conditions for Electrodeposition of Ni-Co/WC Composite Coatings on Red Copper from Sulfate Bath[J].Plating & Finishing,2021,(1):30.[doi:10.3969/j.issn.1001-3849.2021.06.007]

备注/Memo

备注/Memo:
收稿日期： 2019-07-15；修回日期： 2019-08-11
通信作者： 李晓峰， email: lixiaofeng630@163.com
基金项目： 河南省科技攻关项目（182102210163）
更新日期/Last Update: 2020-01-10